936745-40-3

Upstream product

• 120001-35-6 ((4-bromopent-4-en-1-yl)oxy)(tert-butyl)dimethylsilane 
• 64180-78-5 4-bromopent-4-en-1-ol 
• 929295-87-4 acetic acid 1-{1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-vinyl}-2-methyl-3-phenyl-allyl ester 
• 929295-83-0 4-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-2-methyl-1-phenyl-penta-1,4-dien-3-ol 
• 929295-91-0 acetic acid 1-[1-(3-hydroxy-propyl)-vinyl]-2-methyl-3-phenyl-allyl ester 
• 929295-95-4 acetic acid 1-[1-(3-azido-propyl)-vinyl]-2-methyl-3-phenyl-allyl ester 

Downstream Products

• 929295-99-8 4-(3-azido-propyl)-2-methyl-1-phenyl-penta-1,4-dien-3-one 

Relevant academic research and scientific papers

Intramolecular azide trapping of the Nazarov intermediate: Formation of peroxy-bridged indolizidinones via a deep-seated rearrangement and aerobic oxidation

Cross-conjugated dienones with pendent azide side chains undergo interrupted Nazarov trapping, leading to peroxy-bridged indolizidinones in good yields. This process is proposed to involve skeletal rearrangement of the initial trapping product, with loss