936800-12-3Relevant academic research and scientific papers
Palladium(0)-catalyzed Domino C?N Coupling/Hydroamination/C?H Arylation: Efficient Synthesis of Benzothieno[2′,3′:4,5]pyrrolo[1,2-f]phenanthridines
Salman, Ghazwan Ali,Pham, Ngo Nghia,Ngo, Thang Ngoc,Ehlers, Peter,Villinger, Alexander,Langer, Peter
, p. 1402 - 1406 (2017)
Two new and efficient routes to benzothieno[2′,3′:4,5]pyrrolo[1,2-f]phenanthridines have been developed. Alkynylated benzothiophenes reacted with various anilines to the target compounds in a domino reaction consisting of a C?N coupling-, hydroamination-
Nucleophilic Activation of Hydrosilanes via a Strain-Imposing Strategy Leading to Functional Sila-aromatics
Ikeuchi, Toshiya,Hirano, Keiichi,Uchiyama, Masanobu
supporting information, p. 4879 - 4885 (2021/04/06)
Carefully designed cyclic hydrosilanes enable trans-selective hydrosilylation of unactivated alkynes without transition metal catalysts via silicate formation. Employment of sterically demanding bidentate ligands of silicon increases steric congestion upo
Domino C-N coupling/annulation versus C-N coupling/ hydroamination of 2-alkynyl-3-bromobenzothiophenes and 2-alkynyl-3-bromothiophenes. highly efficient synthesis of benzothieno[3,2-b]quinolines and thieno[3,2-b]pyrroles
Salman, Ghazwan Ali,Hussain, Munawar,Iaroshenko, Viktor,Villinger, Alexander,Langer, Peter
scheme or table, p. 331 - 336 (2011/04/16)
While the palladium-catalyzed reaction of 2-alkynyl-3-bromothiophenes with anilines afforded thienopyrroles by a domino C-N coupling/hydroamination process, the reaction of 2-alkynyl-3-bromobenzothiophenes with anilines resulted, under identical condition
Mechanistic study on rearrangement cascades starting from annulated 2-Aza-hepta-2,4-dienyl-6-ynyl anions: Formation of aniline and azepine derivatives
Lyaskovskyy, Volodymyr,Froehlich, Roland,Wuerthwein, Ernst-Ulrich
, p. 3113 - 3119 (2008/02/05)
Deprotonation of benzothiophene-derived alkynyl imine 11 with lithium diisopropylamide (LDA) and subsequent transmetalation with ZnCl2 etherate furnished azepine 12 upon aqueous workup. Similarly, alkynyl benzaldimine la gave a mixture of benza
Large geometrical structure changes of photochromic diarylethenes upon photoirradiation
Morimitsu, Kentaro,Kobatake, Seiya,Irie, Masahiro
, p. 1155 - 1158 (2007/10/03)
Photochromic diarylethene derivatives having phenylethynyl and pent-1-ynyl groups at the reactive carbons have been synthesized. These ethynyl groups enhance the cycloreversion quantum yields of diarylethenes without affecting the absorption maxima and th
