93681-98-2

Basic information

• Product Name: Benzene, 1-[(1-ethylhexyl)thio]-4-methyl-, (S)-
• CAS NO: 93681-98-2
• Molecular Formula: C15H24S
• Molecular Weight: 236.422
• Mol File: 93681-98-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[(1-ethylhexyl)thio]-4-methyl-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[(1-ethylhexyl)thio]-4-methyl-, (S)-(93681-98-2)
• EPA Substance Registry System: Benzene, 1-[(1-ethylhexyl)thio]-4-methyl-, (S)-(93681-98-2)

Safety Data

• Hazardous Substances Data: 93681-98-2(Hazardous Substances Data)

Upstream product

• 589-98-0 (R)-octan-3-ol 
• 106-68-3 3-octanone 
• 93681-97-1 3-octyl methanesulfonate 
• 106-45-6 para-thiocresol 

Downstream Products

• 93682-00-9 (S)-(-)-3-octyl p-tolyl sulfone 

Relevant articles and documents

Studies on Chiral Organo-Sulfur Compounds. II. Stereochemistry of Thermal Chiral Allyl Sulfinate-Sulfone Rearrangements

A highly efficient and general synthetic route to optically active sulfinates by the stereospecific boron trifluoride etherate-catalyzed esterification of sulfinamides was developed.Dramatic solvent effects were observed in the thermal transformation of allyl sulfinate derivatives to sulfones.Heating of chiral trans- and cis-allyl sulfinates, (S)-(-)-3a,c,e and (S)-(-)-3b,d,f, in N,N-dimethylformamide at 90-120 deg C provided chiral sulfones (S)-(+)- and (R)-(-)-5,6,7 in good yields, respectively, with exceedingly high stereospecificity. Keywords - asymmetric transfer; stereospecificity; chiral allyl sulfinate; chiral allyl sulfone; boron trifluoride etherate; thermolysis