936947-85-2

Upstream product

• 936947-84-1 3,6-dideoxy-3,6-(N-benzylamino)-5,7-di-O-benzyl-1,2-O-isopropylidene-α-D-glycero-d-glucohepto-1,4-furanose 
• 936947-82-9 ethyl-3,6-dideoxy-6-diazo-3-benzyloxycarbonylamino-1,2-O-isopropylidene-α-D-xylohept-5-ulofuranuronate 
• 936947-81-8 ethyl-3,6-dideoxy-3-benzyloxycarbonylamino-1,2-O-isopropylidene-α-D-xylohept-5-ulofuranuronate 
• 936947-83-0 ethyl-3,6-dideoxy-3,6-benzyloxycarbonylamino-1,2-O-isopropylidene-α-D-xylohept-5-ulofuranuronate 
• 936947-80-7 (5-formyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl)-carbamic acid benzyl ester 

Relevant academic research and scientific papers

Rh(II)-catalyzed intramolecular N-H insertion of D-glucose-derived δ-amino α-diazo β-ketoester: Synthesis of pyrrolidine iminosugars

The rhodium acetate catalyzed reaction of D-glucose-derived δ-amino α-diazo β-ketoester allows a stereoselective β-facial intramolecular N-H insertion reaction that leads to formation of the bicyclic pyrrolidinone ring skeleton in high yield. The sugar-su