93702-91-1Relevant academic research and scientific papers
Site-Selective and Regioselective Cycloaddition of N-Propadienylanilines with Nitrile Oxides. Claisen-Type Rearrangement of the Cycloadducts
Broggini, Gianluigi,Zecchi, Gaetano
, p. 1843 - 1846 (2007/10/02)
The reaction of N-propadienylanilines with 3,5-dichloro-2,4,6-trimethylbenzonitrile oxide proceeds in a site-selective and regioselective fashion to give 5-substituted 4-methylene-4,5-dihydroisoxazoles.The latter compound (i) add a second molecule of nitr
REACTION OF YNAMINES WITH BIFUNCTIONAL REAGENTS
Sokolova, E. A.,Maretina, I. A.,Petrov, A. A.
, p. 1500 - 1505 (2007/10/02)
The reaction of 1-diethylamino- and 1-(ethylphenylamino)-1-propynes with aromatic and aliphatic bifunctional reagents was invectigated.In the reactions of the ynamines with aromatic binucleophiles and also with ethenolamine and ethylenediamine heterocyclic compounds of the benzodioxole, benzimidazoline, benzoxazole, benzothiazole, oxazoline, and imidazoline series are formed.The reactions of the ynamines with ethylene glycol and dithioglycol gave amino(alkoxy)alkenes and amino(alkylthio)-alkenes.
