93733-50-7

Basic information

• Product Name: Benzenemethanol, a-[[[(4-nitrophenyl)methylene]amino]methyl]-
• CAS NO: 93733-50-7
• Molecular Formula: C15H14N2O3
• Molecular Weight: 270.288
• Mol File: 93733-50-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-[[[(4-nitrophenyl)methylene]amino]methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-[[[(4-nitrophenyl)methylene]amino]methyl]-(93733-50-7)
• EPA Substance Registry System: Benzenemethanol, a-[[[(4-nitrophenyl)methylene]amino]methyl]-(93733-50-7)

Safety Data

• Hazardous Substances Data: 93733-50-7(Hazardous Substances Data)

Upstream product

• 555-16-8 4-nitrobenzaldehdye 
• 7568-93-6 2-Amino-1-phenylethanol 
• 619-73-8 4-nitrobenzyl chloride 

Downstream Products

• 102488-32-4 N-(2'-phenyl-2'-tert-butyldimethylsiloxyethyl)-1-(4'-nitrophenyl)imine 
• 13866-51-8 2-(4-nitrophenyl)-5-phenyl-4,5-dihydro-1,3-oxazole 
• 97958-30-0 cis-4-(4'-nitrophenyl)-3-phenoxy-1-(2'-phenyl-2'-hydroxyethyl)azetidin-2-one 
• 102488-33-5 (3S,4R)-1-[2-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-ethyl]-4-(4-nitro-phenyl)-3-phenoxy-azetidin-2-one 
• 102488-28-8 cis-4-(4'-nitrophenyl)-3-phenoxy-1-(2'-phenyl-2'-oxoethyl)azetidin-2-one 
• 97934-59-3 2-(4'-nitrophenyl)-3-phenoxy-5-phenyloxazolidine 

Relevant articles and documents

Use of Hypervalent Iodine in the Synthesis of Isomeric Dihydrooxazoles

[Figure not available: see fulltext.] A convenient synthesis of 2- and/or 3-oxazolines has been developed depending on the structure and stereochemistry of the starting amino alcohol. PhI(OAc)2 acted as oxidant on the intermediate imine, as sup

Synthesis of β-lactams from acetic acids and imines induced by phenyl dichlorophosphate reagent

The development of a practical method for the preparation of vinylamino-β-lactams from Dane salts and Schiff bases is described. Among the reagents known to produce β-lactams from imines and acetic acids, only phenyl dichlorophosphate and 1-methyl-2-chloropyridinium iodide are suitable for the synthesis of vinylamino-β-lactams. Reaction of acetic acids with ethanolimine derivatives promoted by phenyl dichlorophosphate affords oxazolidines instead of β-lactams. Protection of the hydroxyl group as the trimethylsilyl ether in the starting Schiff bases provides a convenient route to the corresponding β-lactams instead of oxazolidines. Some observations on the scope of the method are made.