937369-06-7Relevant articles and documents
Gold-catalyzed reactivity of 3-silyloxy-1,5-enynes: a synthetic tool for the synthesis of complex structures and its limitations
Menz, Helge,Binder, J?rg T.,Crone, Benedikt,Duschek, Alexander,Haug, Timm T.,Kirsch, Stefan F.,Klahn, Philipp,Liébert, Clémence
experimental part, p. 1880 - 1888 (2009/06/20)
Gold-catalyzed reactions of 3-silyloxy-1,5-enynes in the presence of sterically demanding alcohols afford 4-acylcyclopentenes. The cascade process most likely proceeds through a 6-endo-dig carbocyclization and subsequent pinacol-type rearrangement. Studie