937375-93-4Relevant academic research and scientific papers
Lithiation-induced migrations from nitrogen to carbon in terminal aziridines
Hodgson, David M.,Humphreys, Philip G.,Xu, Zhaoqing,Ward, John G.
, p. 2245 - 2248 (2007)
(Chemical Equation Presented) Benefiting from deprotection: Lithium 2,2,6,6-tetramethylpiperidide induces N-Boc or N-phosphonate terminal aziridines to undergo regio- and stereoselective N-to-C migration of the protecting group, giving synthetically valua
α,β-Aziridinylphosphonates by lithium amide-induced phosphonyl migration from nitrogen to carbon in terminal aziridines
Hodgson, DaviD. M.,Xu, Zhaoqing
supporting information; experimental part, p. 978 - 983 (2011/03/22)
N-Phosphonate terminal aziridines undergo lithium 2,2,6,6- tetramethylpiperidide-induced N-to C-[1,2]-anionic phosphonyl group migration under experimentally straightforward conditions, to provide a stereocontrolled access to synthetically valuable trans-
