93756-85-5Relevant academic research and scientific papers
Unusually Coordinated Phosphorus Compounds; 22. Cycloaddition Reactions of Nitrilium Betaines with a Stable Phosphaalkyne
Roesch, W.,Regitz, M.
, p. 689 - 693 (2007/10/02)
(2,2-Dimethylpropylidyne)phosphane (7) undergoes regiospecific -cycloaddition reactions with the arylnitrile oxides 2a-c to yield the 1,2,4-oxazaphospholes 8a-c.In the reaction of phosphaalkyne 7 with 2,2-dimethylpropanenitrile oxide (2d) the 1:2-adduct 10 is formed in addition to 8d.The reaction of 7 with the nitrile sulphide 12 produces the 1,2,4-thiazaphosphole 13.The 1H-1,2,4-diazaphospholes 18a-c are obtained from the reactions of 7 with the nitrile imines 17a-c; the regioisomers 21a and 21b have been detected by NMR spectroscopy.
1H-1,2,4 λ3-DIAZAPHOSPHOLE AUS 1,3,4-OXADIAZOLIUMSALZEN BZW. SYDNONEN
Maerkl, Gottfried,Pflaum, Siegfried
, p. 4415 - 4418 (2007/10/02)
1-Aryl(alkyl)-1,2,4λ3-diazaphospholes are obtained by the reaction of the title educts with tris-(trimethylsilyl)-phosphane resp. 1-chloro-2-phenyl-2-trimethylsilyl-1-phosphaethene
