93775-88-3Relevant academic research and scientific papers
Acidite de Broensted des phosphoranes a liaison P-H; identification de leurs bases conjuguees; determination de leur pKa
Garrigues, B.,Boyer, D.,Munoz, A.
, p. 2170 - 2178 (2007/10/02)
The P-H proton of phosphoranes containing an α-hydroxy acid or iminodiacetic acid ligand is sufficiently mobile to be removed at room temperature by medium strength bases such as triethylamine.The deprotonation products identified by 31P nmr are (a) the p
Proprietes nucleophiles des phosphoranures
Garrigues, B.,Munoz, A.
, p. 2179 - 2185 (2007/10/02)
The reaction of various bases with P-H bond-containing phosphoranes bearing α-hydroxy acid, α-aminoacid, or iminodiacetic ligands leads to the formation of phosphoronates which react with electrophiles such as alkyl halides, phenyl azide, carbon disulfide
