937801-06-4

Basic information

• Product Name: [(N(CH₂CH₂NSiMe₃)3)Zr(phenylphosphido)]
• Synonyms: [(N(CH₂CH₂NSiMe₃)3)Zr(phenylphosphido)]
• CAS NO: 937801-06-4
• Molecular Weight: 560.069
• Mol File: 937801-06-4.mol

Chemical Properties

• CAS DataBase Reference: [(N(CH₂CH₂NSiMe₃)3)Zr(phenylphosphido)](CAS DataBase Reference)
• NIST Chemistry Reference: [(N(CH₂CH₂NSiMe₃)3)Zr(phenylphosphido)](937801-06-4)
• EPA Substance Registry System: [(N(CH₂CH₂NSiMe₃)3)Zr(phenylphosphido)](937801-06-4)

Safety Data

• Hazardous Substances Data: 937801-06-4(Hazardous Substances Data)

Upstream product

• 937801-05-3 [(N(CH₂CH₂NSiMe₃)3)ZrMe] 
• 638-21-1 phenylphosphane 
• 937801-07-5 [κ⁵-N,N,N,N,C-(Me₃SiNCH₂CH₂)₂NCH₂CH₂NSiMe₂CH₂]Zr 
• 937801-09-7 (N(CH₂CH₂NSiMe₃)₃)ZrCl 

Downstream Products

• 959422-21-0 (N(CH₂CH₂NSiMe₃)3)ZrC(PHPh)=NCH₂Ph 
• 959422-22-1 (N(CH₂CH₂NSiMe₃)3)ZrN(CH₂Ph)C(H)=PPh 
• 1227936-23-3 [(N(C₂H₄NSi(CH₃)3)3)Zr(OC(CH₃)2PHC₆H₅)] 
• 1417624-69-1 C₃₁H₅₆N₅PSi₃Zr 
• 1417624-67-9 C₂₈H₅₆N₅PSi₃Zr 
• 1417624-66-8 C₂₆H₅₄N₅PSi₃Zr 
• 1417624-65-7 C₃₁H₅₆N₅PSi₃Zr 
• 1417624-64-6 C₂₉H₅₁ClN₅PSi₃Zr 
• 1417624-63-5 C₂₈H₅₀N₅PSi₃Zr 

Relevant articles and documents

General preparation of (N3N)ZrX (N3N = N(CH 2CH2NSiMe3)33-)

A homoleptic triamidoamine zirconium complex featuring a metalated trimethylsilyl substituent, [κ5-(Me3SiNCH 2CH2)2NCH2CH2NSiMe 2CH2]Zr (1), was synthesized

Selective dehydrocoupling of phosphines by triamidoamine zirconium catalysts

New zirconium triamidoamine complexes (N3N)ZrR (N3N = N(CH2CH2NSiMe3)33- R = Me, 1; PHPh, 2; PHCy, 4) are effective catalysts for the dehydrocoupling of primary and secondary pho

Zirconium-catalyzed heterodehydrocoupling of primary phosphines with silanes and germanes

Triamidoamine-supported zirconium complexes catalyze the heterodehydrocoupling of primary phosphines with silane and germanes. In this catalysis, P-Si or P-Ge products are observed exclusively with no competitive P-P bond formation. Phosphido complexes (N