93803-26-0Relevant academic research and scientific papers
Synthesis and photophysical properties of two novel branched pyridinium inner salt dyes
Chen, Huihui,Liu, Zhiqiang,Cao, Duxia,Deng, Yunlong,Sun, Yunhui,Li, Fuyou
, p. 563 - 568 (2013)
Two new branched pyridinium inner salt dyes, 2,6-di[2-(N-ethyl-carbazole-3- yl)vinyl]-N-(3-sulfonatepropyl)pyridinium, inner salt (2) and 2,4,6-tri[2-(N-ethyl-carbazole-3-yl)vinyl]-N-(3-sulfonatepropyl)pyridinium, inner salt (3), with N-ethyl-carbazolyl as electron donor group and pyridine cation as electron acceptor group have been synthesized. Their single- and two-photon related fluorescence properties in various solvents have also been examined. These dyes exhibit stronger fluorescence emission relative to the corresponding linear counterpart and common pyridinium dyes with discrete cation and anion components. Three-branched organic dye 3 has a high fluorescence quantum yield as 0.12 and exhibits strong orange two-photon excited fluorescence at 608 nm in THF with large two-photon absorption cross-section being 606 GM.
Dielectric Increments, Intercharge Distances and Conformation of Quaternary Ammonioalkylsulfonates and Alkoxydicyanoethenolates in Aqueous and Trifluoroethanol Solutions
Galin, Monique,Chapoton, Alain,Galin, Jean-Claude
, p. 545 - 553 (2007/10/02)
ω-(Triethylammonio)alkane-α-sulfonates (H5C2)3N+-(CH2)n-SO3- (n=2-4), pyridinio-, 2,6-lutidinio- and N-methylimidazolinio-propanesulfonates , and triethylammonioalkoxydicyanoethenolates (H5C2)3N+-(CH2)n-O-CO-C-(CN)2 (n=2, 3) have been studied by dielectric measurements (1 MHz-1 GHz) in dilute aqueous or trifluoroethanol solution.Their interchange distances have been derived from their dipole moments (μ in the range 18-30 D) calculated according to Buckingham's theory, and compared with the maximum and minimum intercharge distances estimated by molecular mechanics for the ideal fully extended and ion-pair conformations respectively.For identical tether length, stronger charge delocalization in the cationic (imidazolinium versus pyridinium) or anionic (dicyanoethenolate versus sulfonate) sites slightly increases the interchange distance, while better specific solvation of the zwitterions by hydrogen bonding in the less dissociating trifluoroethanol does not result in any significant conformational change with respect to aqueous solutions.Folding of the intercharge arm, negligible for 2-(triethylammonio)ethane-1-sulfonate, progressively increases with its length, but the ion-pair conformation, where the interchange distance becomes rapidly intensive to the tether length, is never reached.This behaviour is in good agreement with the variations of the apparent ΔpKa values of the zwitterions (normalized to that of n-C4H9SO3H) measured by potentiometry in acetic anhydride-acetic acid (9:1, v/v) solution.
