938112-15-3Relevant academic research and scientific papers
Palladacycle as highly efficient catalyst for ring opening of oxabicyclic alkenes with organozinc halides
Zhang, Ting-Ke,Yuan, Ke,Hou, Xue-Long
, p. 1912 - 1919 (2007)
Ring opening reaction of oxabicylic alkenes 4 with in situ prepared organozinc halides 5 was catalyzed by palladacycle 3 with high efficiency. Good yields of the corresponding 1,2-dihydronaphth-1-ols (6) were provided when as low as 0.05 mol% of palladacycle 3 was used. 31P NMR study showed that the skeleton of 3 remained intact in the reaction, which implied that palladacycle 3 did not serve as a catalyst precursor but a catalyst in the reaction.
