93832-40-7Relevant academic research and scientific papers
SYNTHESIS OF TRIQUINACENE DERIVATIVES NEW APPROACH TOWARDS THE SYNTHESIS OF DODECAHEDRANE
Carceller, Elena,Garcia, M. Lluisa,Moyano, Albert,Pericas, Miquel A.,Serratosa, Felix
, p. 1831 - 1840 (1986)
Different synthetic approaches to tricyclo4,10>decane-2,5,8-trione (2) - a triquinacene derivative especially designed for a convergent and reflexive synthesis of dodecahedrane (1) - have been explored, the acetylenic approach through a
An Improved Synthesis of Triquinacene Derivatives. Two-step Regioselective Oxidation of endo-Dicyclopentadiene to Deslongchamps's Diketone
Carceller, Elena,Garcia, M. Lluisa,Moyano, Albert,Serratosa, Felix
, p. 825 - 826 (2007/10/02)
endo-Dicyclopentadiene can be regioselectively oxidised, in two steps, to Deslongchamps's diketone (3), from which either 2,3-dihydrotriquinacen-2-one (13) or the corresponding conjugated ketone (14) can be selectively prepared in excellent overall yields.
