938449-01-5

Upstream product

• 938448-97-6 (4S,5S)-4-benzyl-5-[(E)-3-chloroprop-1-enyl]-4,5-dihydro-2-phenyloxazole 
• 1221966-78-4 (S,E)-N-(6-chloro-3-oxo-1-phenylhex-4-en-2-yl)benzamide 
• 208935-28-8 (4S-trans)-4,5-dihydro-4-benzyl-2-phenyl-5-vinyloxazoline 
• 938448-89-6 methyl (E)-3-[(4S,5S)-4-benzyl-4,5-dihydro-2-phenyloxazol-5-yl]acrylate 
• 938448-93-2 (E)-3-[(4S,5S)-4-benzyl-4,5-dihydro-2-phenyloxazol-5-yl]prop-2-en-1-ol 

Downstream Products

• 938449-05-9 N-[(E,2S,3S)-3-(tert-butyldimethylsilyloxy)-6-chloro-1-phenylhex-4-en-2-yl]benzamide 

Relevant academic research and scientific papers

Stereoselective intramolecular cyclization of γ-allylbenzamide via π-allylpalladium complex catalyzed by Pd(0)

An efficient procedure for synthesizing oxazines was developed by the palladium(0)-catalyzed intramolecular cyclization of a benzamide through a π-allylpalladium (II) complex. Interestingly, the diastereoselectivity of oxazine ring formation was dominantly controlled by the bulkiness of various protecting groups on the secondary alcohols.

Stereoselective intramolecular oxazine formation by a π-allylpalladium complex catalyzed by Pd0

An efficient procedure for synthesizing oxazines was developed by the palladium(0)-catalyzed intramolecular cyclization of a benzamide through a π-allylpalladium(II) complex. Unlike other palladium-catalyzed reactions, the temperature was found to be a ke