939-60-6Relevant academic research and scientific papers
SYNTHESIS OF UNSATURATED TERTIARY AMINES AND α-ALLYL SUBSTITUTED KETONES FROM AZOMETHINES USING METAL COMPLEX CATALYSTS
Ibragimov, A. G.,Minsker, D. L.,Morozov, A. B.,Galkin, E. M.,Dzhemilev, U. M.,Tolstikov, G. A.
, p. 140 - 144 (2007/10/02)
A method has been developed for the regioselective synthesis of unsaturated tertiary amines via the reaction of magnesium amides, derived from Schiff bases, with allylic electrophiles in the presence of Pd and Cu complexes.The reaction of ketimines which
Highly Regio- and Stereospecific Palladium-Catalyzed Allylation of Enolates Derived from Ketones
Negishi, Ei-ichi,Matsushita, Hajime,Chatterjee, Sugata,John, Robert A.
, p. 3188 - 3190 (2007/10/02)
The reaction of potassium enoxyborates, readily obtainable by treating potassium enolates with a trialkylborane, e.g., triethylborane, with allylic electrophiles such as allylic chlorides and acetates in the presence of a catalytic amount of a palladium-p
