939401-38-4Relevant academic research and scientific papers
Gold(I)-catalyzed [2 + 2]-cycloaddition of allenenes
Luzung, Michael R.,Mauleon, Pablo,Toste, F. Dean
, p. 12402 - 12403 (2008/09/17)
A cationic phosphinegold(I)-catalyzed intramolecular [2 + 2]-cycloaddition between an allene and an alkene to form alkylidene?cyclobutanes is described. Additionally, the reported cycloisomerization reaction provides access to enantioenriched bicyclo-[3.2.0] structures using chiral biarylphosphinegold(I) complexes as catalysts. Copyright
Heck arylations of pent-4-enoates or allylmalonate using a palladium/tetraphosphine catalyst
Lemhadri, Mhamed,Battace, Ahmed,Zair, Touriya,Doucet, Henri,Santelli, Maurice
, p. 2270 - 2281 (2007/10/03)
The Heck reaction of aryl halides with functionalised alk-1-enes should be a powerful method for the synthesis of functionalised (E)-1-arylalk-1-ene derivatives. The major problem of this reaction is the palladium-catalysed migration of the carbon-carbon
