93958-18-0Relevant academic research and scientific papers
Dimethyl(alkylthio)- and Dimethyl(arylthio)gallanes - Synthesis and Properties
Hoffmann, Gerhard G.
, p. 1216 - 1218 (2007/10/02)
The nucleophilic substitution reactions between dimethylgalliumchloride (1) and the silyl sulfides (CH3)3SiSR (R = CH3, C2H5, n-C3H7, i-C3H7, Ph and CH2Ph) (2-7) in benzene result in the formation of the moisture-sensitive dimethyl(alkylthio)- and dimethyl(phenylthio)gallanes (CH3)3GaSR (R = CH3, C2H5, n-C3H7, i-C3H7, Ph and CH2Ph) (8-13).Compounds 8-11 are trimeric in benzene solutions, whereas compounds 12 and 13 appeared to be monomeric.The synthesis of dimethylgalliumchloride starting from trimethylgallane or methylgalliumdichloride and galliumtrichloride is reported as well. - Keywords: Dimethylgalliumchloride, Dimethyl(alkylthio)- and Dimethyl(arylthio) Compounds, Synthesis, Properties
