93965-56-1Relevant academic research and scientific papers
Regiospecific and Diastereoselective Crotylation of Aldimines with Crotylfluorosilanes Activated by Fluoride Ions
Kira, Mitsuo,Hino, Takakazu,Sakurai, Hideki
, p. 277 - 280 (2007/10/02)
Aliphatic and aromatic aldimines are crotylated in a regiospecific and diastereoselective manner by the reaction with (E)- and (Z)-crotyltrifluorosilanes in the presence of cesium fluoride to give homoallylamines in high yields.
Homoallylamines from Aldimines and Allylstannanes
Keck, Gary E.,Enholm, Eric J.
, p. 146 - 147 (2007/10/02)
Allyltri-n-butylstannane adds to aldimines in the presence of Lewis acids to give homoallylamines; for the analogous additions of crotyltri-n-butylstannane, bond construction selectivity is a sensitive function of the thermal history of the aldimine-Lewis
