93998-08-4

Basic information

• Product Name: 3,7-dimethyl-1-phenyl-3-vinyloct-6-en-1-one
• Synonyms: 3,7-dimethyl-1-phenyl-3-vinyloct-6-en-1-one
• CAS NO: 93998-08-4
• Molecular Weight: 256.388
• Mol File: 93998-08-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3,7-dimethyl-1-phenyl-3-vinyloct-6-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3,7-dimethyl-1-phenyl-3-vinyloct-6-en-1-one(93998-08-4)
• EPA Substance Registry System: 3,7-dimethyl-1-phenyl-3-vinyloct-6-en-1-one(93998-08-4)

Safety Data

• Hazardous Substances Data: 93998-08-4(Hazardous Substances Data)

Upstream product

• 106-24-1 Geraniol 
• 4747-13-1 α-methoxystyrene 
• 13735-81-4 1-styrenyloxytrimethylsilane 
• 117969-60-5 (2E)-1-fluoro-3,7-dimethylocta-2,6-diene 
• 1438282-92-8 (E)-(3,7-dimethylocta-2,6-dien-1-yl)boronic acid 
• 94-48-4 (E)-geranyl benzoate 

Relevant articles and documents

Beyond the Tebbe Olefination: Direct Transformation of Esters into Ketones or Alkenes

A direct, effective, and operationally simple transformation of esters into ketones or alkenes by the exclusive action of Tebbe's reagent has been developed. The transformation utilizes the dual character of Tebbe's reagent as both a methylenation agent and a rearrangement catalyst in the reaction of a wide range of substituted vinyl ethers. The resulting transformation involves sequential methylenation and rearrangement reactions and it offers a high degree of selectivity toward the synthesis of ketones or alkenes. The scope and limitations of the developed methods have been also examined.

Boron trifluoride-catalyzed reaction of alkyl fluoride with silyl enolate, allylsilane, and hydrosilane

Alkylation of silyl enolates with tert-alkyl or allylic fluorides proceeds smoothly in the presence of a catalytic amount of boron trifluoride to afford the corresponding carbonyl compounds. Allylation and reduction of alkyl fluorides with allylsilane and hydrosilane, respectively, occur under BF 3 catalysis.