939985-35-0Relevant academic research and scientific papers
Transition-metal-catalyzed rearrangement of allenyl sulfides: A route to furan derivatives
Peng, Lingling,Zhang, Xiu,Ma, Ming,Wang, Jianbo
, p. 1905 - 1908 (2008/03/12)
(Chemical Equation Presented) Mass migration: Allenyl sulfides undergo 1,4-migration of the phenylsulfanyl group when catalyzed by a transition-metal complex to give furan derivatives (see scheme). Evidence suggests that the reaction proceeds via a metal
1,2-Sulfanyl group migration as a driving force: New approach to pyrroles by reaction of allenic aldehydes with amines
Peng, Lingling,Zhang, Xiu,Ma, Jie,Zhong, Zhenzhen,Wang, Jianbo
, p. 1445 - 1448 (2008/02/02)
Equation presented Acid-promoted reaction of sulfanyl group substituted allenic aldehyde with amine affords pyrrole derivatives in high yields. The neighboring group participation of the sulfanyl group is the driving force in this transformation.
