94079-61-5Relevant academic research and scientific papers
Synthesis of pyrroles via copper-catalyzed coupling of amines with bromoenones
Pan, Yuanjia,Lu, Hongjian,Fang, Yewen,Fang, Xinqiang,Chen, Liqun,Qian, Junlu,Wang, Junhua,Li, Chaozhong
, p. 1242 - 1246 (2008/02/02)
The CuI/N,N-dimethylglycine hydrochloride catalyzed reactions of amines with γ-bromo-substituted γ,δ-unsaturated ketones in the presence of K3PO4 and NH4OAc led to the formation of the corresponding polysubstituted pyrrole
One-pot synthesis of N-substituted 2-methyl-4,5,6,7-tetrahydroindole derivatives
Tanyeli, Cihangir,Akhmedov, Idris M.,Yazicio?lu, Emre Y.
, p. 9627 - 9629 (2007/10/03)
We describe the preliminary results of one-pot syntheses of various N-substituted 2-methyl-4,5,6,7-tetrahydroindole derivatives from 2-(2-bromoallyl)cyclohexanone and the corresponding primary amines in good yields. Aliphatic amines were directly converted to tetrahydroindoles, whereas aromatic amines needed an extra base treatment step to complete the transformation.
