94089-49-3

Upstream product

• 53068-89-6 (R)-(+)-2-(2'-carbomethoxyethyl)-2-methylcyclohexanone 
• 583-60-8 2-Methylcyclohexanone 
• 19980-35-9 1-trimethylsilyloxy-2-methyl-1-cyclohexene 

Relevant academic research and scientific papers

Palladium-Catalyzed Decarbonylative Dehydration for the Synthesis of α-Vinyl Carbonyl Compounds and Total Synthesis of (-)-Aspewentins A, B, and C

The direct α-vinylation of carbonyl compounds to form a quaternary stereocenter is a challenging transformation. It was discovered that δ-oxocarboxylic acids can serve as masked vinyl compounds and be unveiled by palladium-catalyzed decarbonylative dehydr

Asymmetric michael reactions : Enantioselective synthesis of δ-oxo-acids

β-substituted and α,β-disubstituted δ-oxo acids are synthesized with high enantiomeric excess from chiral 2-propenyl oxazolines 8 and 11, whilst 2-vinyl oxazlines 7 and 10 are less efficient asymmetric inductors.