940912-19-6Relevant articles and documents
Stereoselective dioxirane hydroxylations and the synthesis of tripod boronic acid esters
D'Accolti, Lucia,Fiorentino, Michele,Fusco, Caterina,Capitelli, Francesco,Curci, Ruggero
, p. 3575 - 3578 (2007)
Methyl(trifluoromethyl)dioxirane (TFDO, 1b), a powerful yet selective oxidant, was employed to achieve in high yield the direct stereoselective hydroxylation at tert-CH of cis,cis-1,3,5-trimethylcyclohexane (4), yielding triol 7 bearing all-axial disposit