940965-21-9Relevant academic research and scientific papers
Gold(I)-catalyzed oxidative rearrangements
Witham, Cole A.,Mauleon, Pablo,Shapiro, Nathan D.,Sherry, Benjamin D.,Toste, F. Dean
, p. 5838 - 5839 (2008/02/12)
A series of gold(I)-catalyzed oxidative rearrangement reactions of alkynes using sulfoxides as stoichiometric oxidants are reported. The reactions are postulated to proceed through intermolecular oxygen atom transfer from the sulfoxide to gold(I)-carbenoi
