94112-99-9

Basic information

• Product Name: tetramethyl 5-cyclohexene-1,2,3,4-tetracarboxylate
• Synonyms: tetramethyl 5-cyclohexene-1,2,3,4-tetracarboxylate
• CAS NO: 94112-99-9
• Molecular Weight: 314.292
• Mol File: 94112-99-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tetramethyl 5-cyclohexene-1,2,3,4-tetracarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: tetramethyl 5-cyclohexene-1,2,3,4-tetracarboxylate(94112-99-9)
• EPA Substance Registry System: tetramethyl 5-cyclohexene-1,2,3,4-tetracarboxylate(94112-99-9)

Safety Data

• Hazardous Substances Data: 94112-99-9(Hazardous Substances Data)

Upstream product

• 1119-43-3 (E,E)-hexa-2,4-dienedioic acid dimethyl ester 
• 23055-10-9 1,4-dimethyl but-2-enedioate 
• 3588-17-8 trans,trans-muconic acid 
• 624-49-7 dimethylfumarate 

Downstream Products

• 3451-02-3 benzene-1,2,3,4-tetracarboxylic acid tetramethyl ester 
• 2459-10-1 benzene-1,2,4-tricarboxylic acid trimethyl ester 
• 108013-31-6 tetramethyl 1,2,3,4-cyclohexanetetracarboxylate 
• 108013-31-6 cyclohexane-1r,2t,3t,4c-tetracarboxylic acid tetramethyl ester 
• 108013-31-6 cyclohexane-1r,2c,3c,4c-tetracarboxylic acid tetramethyl ester 

Relevant articles and documents

Sustainable synthesis of 1,2,3,4-cyclohexanetetracarboxylate from sugar-derived carboxylic acids

Herein, we report a sustainable route for the synthesis of 1,2,3,4-cyclohexanetetracarboxylate from sugar-derived muconic acid and fumaric acid. The key Diels-Alder reaction constructed a cyclohexene framework substituted by four ester groups. The isolated yield of tetramethyl 5-cyclohexene-1,2,3,4-tetracarboxylate was up to 95.5percent without any catalyst used. And the hydrogenation reaction of the cycloadduct was catalyzed by commercial RANEY? Ni at room temperature and nearly 100percent yield of the cyclohexyl target products was obtained. This journal is