94119-01-4

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 94118-99-7 1-O-benzyl-2,3-O-isopropylidene-β-L-gulofuranose 
• 74912-02-0 1-O-benzyl-2,3-O-isopropylidene-α-D-manno-furanose 
• 94152-34-8 5,6-di-O-acetyl-1-O-benzyl-2,3-O-isopropylidene-β-L-gulofuranose 
• 28978-37-2 1-O-benzyl-2,3-O-isopropylidene-5,6-di-O-mesyl-α-D-mannofuranose 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 94119-00-3 (S)-1-((3aS,4R,6S,6aS)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethanol 

Downstream Products

• 94119-03-6 5-azido-1-O-benzyl-5-deoxy-2,3-O-isopropylidene-α-D-mannofuranose 
• 94119-04-7 benzyl 5-azido-5-deoxy-α-D-mannofuranoside 
• 94119-02-5 [(R)-2-Azido-2-((3aS,4R,6S,6aS)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-ethoxy]-tert-butyl-diphenyl-silane 

Relevant academic research and scientific papers

SYNTHESES OF 1,5-DIDEOXY-1,5-IMINO-D-MANNITOL FROM D-MANNOSE AND D-GLUCOSE

Unambigous enantiospecific syntheses of 1,5-dideoxy-1,5-imino-D-mannitol (LU1, 1-deoxy-mannojirimycin) are reported (i) from D-mannose via hydrogenation of a 5-azido-5-deoxy mannose, and (ii) from D-glucose, in which the key step involves nucleophilic substitution of a trifluoromethanesulphonyl group from C-2 of D-glucose.