94125-42-5Relevant articles and documents
Soil transformation of prosulfuron
Menniti, Christophe,Cambon, Jean-Pierre,Bastide, Jean
, p. 3525 - 3527 (2003)
The transformation of prosulfuron [1-(4-methoxy-6-methyltriazine-2-yl)-3- [2-(3,3,3-trifluropropyl)-phenylsulfonyl]urea] in three soils at different pH values (sterilized and unsterilized) was studied, and it was shown that the rate of transformation was high in acidic soil. From the results obtained in sterile soils, it is shown that the mechanism of dissipation was mainly chemical in acidic soils. A new metabolite, 2-(3,3,3-trifluoropropyl)phenylsulfonic acid, was identified.
Synthesis method of prosulfuron intermediate
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, (2021/09/05)
The invention discloses a synthesis method of a prosulfuron intermediate 2-(3, 3, 3-trifluoropropyl) benzenesulfonamide, which comprises the following steps: by taking o-chlorobenzyl cyanide and ethyl trifluoroacetate as initial raw materials, firstly carrying out acylation reaction in the presence of organic alkali, then carrying out decyanation reaction in the presence of sulfuric acid, and then carrying out reduction reaction in the presence of a reducing agent, carrying out a dehydration reaction in the presence of a catalyst, carrying out a reduction reaction in the presence of a reducing agent, carrying out a sulfhydrylation reaction with a sulfhydrylation reagent, carrying out a sulfonyl chlorination reaction with chlorine in the presence of water, and carrying out a sulfonylation reaction with ammonia water. Compared with the prior art, the synthesis method has the advantages that the adopted raw materials and auxiliaries are low in cost and easy to obtain, the reaction conditions are mild, the operation is simple and convenient, the safety is higher, the synthesis method is more environment-friendly, the synthesis route is particularly important in the current times with stricter requirements on safety and environmental protection, and the safety of industrial production can be ensured.
N-phenylsulfonyl-N'-triazinylureas
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, (2008/06/13)
N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the formula I STR1 wherein A is 3,3,3-trifluoropropyl or 3,3-difluorobutyl, R1 is hydrogen, halogen, nitro, cyano, C1 -C4 -alkyl, C1 -C4 -haloalkyl, C1 -C4 -alkoxy, C1 -C4 -alkylthio, C1 -C4 -alkylsulfinyl, C1 -C4 -alkylsulfonyl, --CO--R6, --NR7 R8, --CO--NR9 R10 or --SO2 --NR11 R12, R2 is hydrogen, halogen, C1 -C4 -alkyl, C1 -C4 -alkoxy, C1 -C4 -alkylthio, C1 -C4 -alkylsulfinyl or C1 -C4 -alkylsulfonyl, R3 and R4 independently of one another are each hydrogen, halogen, C1 -C4 -alkyl, C1 -C4 -haloalkyl, C2 -C4 -haloalkoxy, C1 -C4 -alkylthio, C1 -C4 -haloalkylthio, C2 -C4 -alkoxyalkyl, C1 -C4 -alkoxy or --NR12 R13, R5 is hydrogen, C1 -C4 -alkyl or C1 -C4 -alkoxy, R6 is C1 -C4 -alkoxy, C1 -C4 -haloalkoxy, C1 -C4 -alkylthio, C2 -C6 -alkoxyalkoxy, hydrogen, C1 -C4 -alkyl or C1 -C4 -haloalkyl, R7, R8, R9, R10, R11, R12 and R13 independently of one another are each hydrogen or C1 -C4 -alkyl, E is nitrogen, and Z is oxygen or sulfur; and also the salts of these compounds.