941270-66-2Relevant academic research and scientific papers
Catalyst-Free S–S Bond Insertion Reaction of a Donor/Acceptor-Free Carbene by a Radical Process: A Combined Experimental and Computational Study
Zheng, Yang,Bian, Rongjian,Zhang, Xiaolu,Yao, Ruwei,Qiu, Lihua,Bao, Xiaoguang,Xu, Xinfang
, p. 3872 - 3877 (2016)
Herein, a donor/acceptor-free carbene insertion reaction of an S–S bond through a radical process is presented. This catalyst-free reaction was thermally induced and provided the dithioketal products in moderate to high yields. A mechanism involving radical intermediates was proposed according to the computational study, and these intermediates were verified experimentally and intercepted for the first time by using a cross-coupling reaction.
An efficient synthesis of aryl α-keto esters
Ma, Ming,Li, Changkun,Peng, Lingling,Xie, Fang,Zhang, Xiu,Wang, Jianbo
, p. 3927 - 3929 (2007/10/03)
A new one-pot approach for the synthesis of aryl α-keto ester based on the diazo transfer and oxidation of diazo group is developed.
