942041-33-0

Upstream product

• 75-24-1 trimethylaluminum 
• 942041-32-9 C₂₀H₂₆O₆ 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 50680-06-3 2-O-Benzoyl-4.6-benzyliden-3-O-(tetrahydropyran-2-yl)-α-D-glucopyranose-methylether 
• 28642-64-0 methyl 4,6-O-benzylidene-2-O-benzoyl-α-D-glucopyranoside 
• 39686-99-2 4.6-O-Benzyliden-3-O-(tetrahydropyran-2-yl)-α-D-glucopyranose-methylether 
• 50680-08-5 (4aR,6S,8S,8aR)-6-Methoxy-2-phenyl-8-(tetrahydro-pyran-2-yloxy)-tetrahydro-pyrano[3,2-d][1,3]dioxin-7-one 
• 3162-96-7 methyl 4,6-O-benzylidene-α-D-glucopyranoside 

Downstream Products

• 142644-81-3 methyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-C-methylene-α-D-arabino-hexopyranosid 
• 942041-39-6 methyl 3,4-di-O-benzyl-2-C-benzyloxymethyl-2-deoxy-α-D-glucopyranoside 
• 942041-40-9 methyl 3,4-di-O-benzyl-2-C-benzyloxymethyl-2,6-dideoxy-6-iodo-α-D-glucopyranoside 
• 163563-92-6 (3S,4R,5R,6S)-3,4-Bis-benzyloxy-5-benzyloxymethyl-6-methoxy-2-methylene-tetrahydro-pyran 
• 163563-91-5 (4R,5R,6S)-5,6-Bis-benzyloxy-4-benzyloxymethyl-cyclohex-2-enone 
• 161596-05-0 (1S,2R,3R,4R)-2,3-di-O-benzyl-4-benzyloxymethylcyclohex-5-ene-1,2,3-triol 
• 161596-04-9 (1R,2R,3R,4R)-2,3-di-O-benzyl-4-benzyloxymethylcyclohex-5-ene-1,2,3-triol 
• 151693-61-7 (1S,2R,3R,4R)-1-O-benzoyl-2,3-di-O-benzyl-4-benzyloxymethylcyclohex-5-ene-1,2,3-triol 
• 142644-83-5 methyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-C-hydroxymethyl-α-D-glucopyranoside 
• 142644-84-6 methyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-C-hydroxymethyl-α-D-mannopyranoside 
• 942041-42-1 C₃₃H₃₃N₅O₃ 
• 942041-41-0 C₂₈H₃₀O₅ 
• 942041-38-5 C₂₉H₃₂O₆ 
• 942041-43-2 C₂₂H₂₄O₆ 

Relevant academic research and scientific papers

Stereoselective synthesis of (-)-ara-cyclohexenyl-adenine

A stereoselective synthesis leading to (-)-ara-cyclohexenyl-adenine is described. The synthesis starts from methyl-α-d-glucopyranose and involves an isomerization step, selective protection/deprotection chemistry, a Ferrier rearrangement and a Mitsunobu r

Some routes to C2-alkoxymethyl hex-2-enopyranosides

Several procedures for installing a C2 alkoxy group at C2 of a hex-2-enopyranoside have been investigated. The one that is most convenient for large-scale preparation begins with a 2-keto pyranoside, which is converted into the corresponding exo methylene derivative. An S(N)2' rearrangement is effected with thionyl chloride, and the resulting primary allylic chloride is displaced with sodium benzylate.