94235-49-1

Upstream product

• 120295-69-4 (7E,9E,11Z,14Z)-(5R,6S)-5,6-Bis-(tert-butyl-dimethyl-silanyloxy)-icosa-7,9,11,14-tetraenoic acid methyl ester 
• 120295-67-2 ((1E,3Z,6Z)-2-Dodeca-1,3,6-trienyl)-benzo[1,3,2]dioxaborole 
• 148553-23-5 (5S)-<5-oxo-(1E,3E)-penta-1,3-dien-1-yl>-2-oxo-1,3-dioxolane-4-butanoate de methyle 
• 127705-14-0 5-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-hydroxy-pentanoic acid 3-hydroxy-2-hydroxymethyl-2-methyl-propyl ester 
• 127721-09-9 (R)-5-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-phenoxycarbonyloxy-pentanoic acid methyl ester 
• 127705-17-3 4-((4R,5S)-5-Hydroxymethyl-2-oxo-[1,3]dioxolan-4-yl)-butyric acid methyl ester 
• 127705-13-9 1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-4-(4-methyl-2,6,7-trioxa-bicyclo[2.2.2]oct-1-yl)-butan-1-ol 
• 79308-47-7 5-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-hydroxy-pentanoic acid methyl ester 
• 120295-76-3 (E)-(5R,6S)-5,6-Bis-(tert-butyl-dimethyl-silanyloxy)-8-iodo-oct-7-enoic acid methyl ester 
• 99017-25-1 (5R,6R)-5,6-Bis-(tert-butyl-dimethyl-silanyloxy)-7-oxo-heptanoic acid methyl ester 
• 120295-73-0 (5R,6S)-(7E,9E,11Z,14Z)-5,6-Dihydroxy-7,9,11,14-icosatetraensaeure-methylester 
• 127996-89-8 (5S)-<(1E,3E,5Z,8Z)-tetradeca-1,3,5,8-tetraen-1-yl>-2-oxo-1,3-dioxolane-4-butanoate de methyle 

Relevant academic research and scientific papers

5-Lipoxygenase-derived oxylipins from the red alga Rhodymenia pertusa

The lipid extract of the temperate red alga Rhodymenia pertusa has yielded four eicosanoid metabolites, three of which are new natural products. Using principally NMR and MS techniques, their structures were deduced as 5R,6S-dihydroxy-7(E),9(E),11(Z),14(Z)-eicosatetraenoic acid (5R,6S-diHETE), 5R*,6S*-dihydroxy-7(E),9(E), 11(Z),14(Z),17(Z)-eicosapentaenoic acid (5R*,6S*-diHEPE), 5-hydroxy-6(E),8(Z),11(Z),14(Z)-eicosatetraenoic acid (5- HETE), 5-hydroxy-6(E),8(Z),11(Z),14(Z),17(Z)-eicosapentaenoic acid (5-HEPE). The co-occurrence of these metabolites strongly suggests that R. pertusa contains a unique 5R-lipoxygenase system acting on both arachidonic and eicosapentaenoic acids.