Cas 94249-86-2,Ir(C6H5CH2CH3)(P(C6H5)3)2(1+)*SbF6(1-) = [Ir(C6H5CH2CH3)(P(C6H5)3)2]SbF6

94249-86-2

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Basic information

Product Name: Ir(C₆H₅CH₂CH₃)(P(C₆H₅)3)2⁽¹⁺⁾*SbF₆^(1-) = [Ir(C₆H₅CH₂CH₃)(P(C₆H₅)3)2]SbF₆
Synonyms: Ir(C₆H₅CH₂CH₃)(P(C₆H₅)3)2⁽¹⁺⁾*SbF₆^(1-) = [Ir(C₆H₅CH₂CH₃)(P(C₆H₅)3)2]SbF₆
CAS NO:94249-86-2
Molecular Formula:
Molecular Weight: 1058.71
EINECS: N/A
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Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: Ir(C₆H₅CH₂CH₃)(P(C₆H₅)3)2⁽¹⁺⁾*SbF₆^(1-) = [Ir(C₆H₅CH₂CH₃)(P(C₆H₅)3)2]SbF₆(CAS DataBase Reference)
NIST Chemistry Reference: Ir(C₆H₅CH₂CH₃)(P(C₆H₅)3)2⁽¹⁺⁾*SbF₆^(1-) = [Ir(C₆H₅CH₂CH₃)(P(C₆H₅)3)2]SbF₆(94249-86-2)
EPA Substance Registry System: Ir(C₆H₅CH₂CH₃)(P(C₆H₅)3)2⁽¹⁺⁾*SbF₆^(1-) = [Ir(C₆H₅CH₂CH₃)(P(C₆H₅)3)2]SbF₆(94249-86-2)

Safety Data

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Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 94249-86-2(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 94249-86-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,4,2,4 and 9 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 94249-86:
(7*9)+(6*4)+(5*2)+(4*4)+(3*9)+(2*8)+(1*6)=162
162 % 10 = 2
So 94249-86-2 is a valid CAS Registry Number.

94249-86-2Upstream product

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94249-86-2Relevant academic research and scientific papers

Arene and cyclohexadienyl complexes as intermediates in the selective catalytic dehydrogenation of cyclohexenes to arenes

Crabtree, Robert H.,Parnell, Charles P.

, p. 519 - 523 (2008/10/08)

A catalytic aromatization of cyclohexene to benzene is described by using [IrH2(Me2CO)2L2]SbF6 (L = PPh3) as catalyst in refluxing 1,2-C2H4Cl2. tert-Butylethylene (tbe) acts as hydrogen acceptor; in the absence of tbe, 2 equiv of cyclohexane are formed per mole of benzene. A mechanism is suggested based on the isolation of the proposed intermediates [Ir(η5-C6H7)HL2]SbF6 and [Ir(η6-C6H6)L2]SbF6. Some reactions of these complexes are discussed.

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