94256-22-1Relevant academic research and scientific papers
Efficient synthesis of xanthenedione derivatives using cesium salt of phosphotungstic acid as a heterogeneous and reusable catalyst in water
Thakur, Ashima,Sharma, Alka,Sharma, Abha
supporting information, p. 1766 - 1771 (2016/10/31)
Cs2.5H0.5PW12O40has been reported to be an efficient catalyst for the synthesis of 1,8-dioxo-octahydroxanthene from aldehydes and 1,3-cyclohexanedione/dimedone in water. This approach is environmentally benign with clean synthetic procedure, short reaction time, easy workup procedure, excellent yield, and regeneration of catalyst, which made this protocol efficient and safe.
Efficient synthesis of 1,8-dioxo-octahydroxanthenes catalyzed by β-cyclodextrin grafted with butyl sulfonic acid in aqueous media
Gong, Kai,Wang, Hualan,Wang, Shuxin,Wang, Ying,Chen, Jinghua
, p. 1249 - 1255 (2015/09/01)
β-Cyclodextrin was functionalized with butyl sulfonic acid to give an efficient, eco-friendly catalyst for the synthesis of 1,8-dioxo-octahydroxanthenes via the one-pot condensation of aromatic aldehydes and active methylene carbonyl compounds in aqueous
Bi-SO3H functionalized ionic liquid based on DABCO as a mild and efficient catalyst for the synthesis of 1,8-dioxo-octahydro-xanthene and 5-arylmethylene-pyrimidine-2,4,6-trione derivatives
Shirini, Farhad,Langarudi, Mohaddeseh Safarpoor Nikoo,Seddighi, Mohadeseh,Jolodar, Omid Goli
, p. 8483 - 8497 (2015/01/30)
1,8-Dioxo-octahydro-xanthenes are easily prepared via the condensation of aldehydes with 1,3-cyclohexadione and/or dimedone using N-sulfonated DABCO as a new and efficient catalyst. This reagent is also efficiently able to catalyze the condensation of aldehydes with barbituric acid leading to 5-arylmethylene-pyrimidine-2,4,6-triones. The structure of the products was characterized by their IR, 1H NMR, and 13C NMR spectroscopy. The present methodology offers several advantages such as ease of preparation and handling of the catalyst, high yields, simple and green procedure, low cost, short reaction times, easy work-up, and preformation of the reaction in the absence of solvent or in water as a green solvent.
Introduction of a new bi-SO3H ionic liquid based on 2,2′-bipyridine as a novel catalyst for the synthesis of various xanthene derivatives
Shirini, Farhad,Abedini, Masoumeh,Seddighi, Mohaddeseh,Jolodar, Omid Goli,Safarpoor, Mohadeseh,Langroodi, Nikoo,Zamani, Solmaz
, p. 63526 - 63532 (2015/02/19)
In this study, 1,1′-disulfo-[2,2′-bipyridine]-1,1′-diium chloride, [BiPy](SO3H)2Cl2 as a new ionic liquid, is prepared, characterized and used as an efficient catalyst for the promotion of the synthesis of various symmetri
Introduction of O-sulfonated poly(4-vinylpyrrolidonium) chloride as a polymeric and reusable catalyst for the synthesis of xanthene derivatives
Shirini, Farhad,Moghadam, Peyman Najafi,Moayedi, Simin,Seddighi, Mohadeseh
, p. 38581 - 38588 (2014/11/08)
O-Sulfonated poly(4-vinylpyrrolidonium) chloride is prepared from the reaction of poly(4-vinylpyrrolidone) [PVP], as a cheap and commercially available reagent, and neat chlorosulfonic acid at room temperature. A variety of techniques including infrared s
N-sulfonic acid poly(4-vinylpyridinium) chloride: A novel polymeric and reusable catalyst for the preparation of xanthenes derivatives
Shirini, Frahad,Abedini, Masoumeh,Pourhasan, Reyhaneh
, p. 250 - 255 (2013/10/21)
A simple and efficient procedure for the preparation of 14-aryl-14H-dibenzo[a,j]xanthenes, 1,8-dioxooctahydroxanthenes and tetrahydrobenzo[a]xanthene-11-ones is described using N-sulfonic acid poly(4-vinylpyridinium) chloride (NSPVPC) as a heterogeneous a
Use of nanoporous Na+-montmorillonite sulfonic acid (SANM) as an eco-benign, efficient and reusable solid acid catalyst for the one-pot synthesis of 14-aryl-14-H-dibenzo[a,j]xanthenes and 1,8-dioxo- dodecahydroxanthene derivatives
Shirini, Farhad,Mamaghani, Manouchehr,Atghia, Seyyed Vahid
, p. 415 - 420 (2013/07/27)
Nanoporous Na+-montmorillonite sulfonic acid was found to be an efficient and green catalyst for the synthesis of various 14-aryl-14H-dibenzo[a, j]xanthenes and 1,8-dioxo-dodecahydroxanthene derivatives by the reaction of aldehydes with 2-napht
A novel polymeric catalyst for the one-pot synthesis of xanthene derivatives under solvent-free conditions
Maleki, Behrooz,Barzegar, Shahram,Sepehr, Zeinalabedin,Kermanian, Mina,Tayebee, Reza
, p. 757 - 765 (2013/02/22)
A simple, efficient, and environmentally benign route was developed for the preparation of 14-aryl or alkyl- 14H-dibenzo[a,j]xanthene, 1,8-dioxo- octahydroxanthene and 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthene-11-ones from condensation of various aldeh
CsF mediated rapid condensation of 1,3-cyclohexadione with aromatic aldehydes: Comparative study of conventional heating vs. ambient temperature
Nandre, Kamalakar P.,Patil, Vijay S.,Bhosale, Sidhanath V.
experimental part, p. 777 - 780 (2012/01/03)
A mild, efficient and high yielding protocol for the synthesis of 2,2′-arylmethelene dicyclohexane-1,3-dione derivatives at room temperature and 9-aryl-1,8-dihydrooctahydroxanthene at conventional heating using cesium fluoride as a catalyst is reported. T
Condensation of 1,3-cyclohexanedione with aromatic aldehydes catalyzed by acidic ionic liquids
Kang, Hui,Hu, Yi,Huang, He,Wei, Ping
scheme or table, p. 223 - 227 (2009/04/14)
An efficient and convenient approach to the synthesis of 9-aryl-2, 3, 4, 5, 6, 7-hexahydro-2H-Xanthene-1, 8-dionc by condensation of 1, 3-cyclohexanedione with aromatic aldehydes catalyzed by acid ionic liquid 1-methyllimidazolium hydrogen sulphate ([Hmim
