94256-60-7Relevant academic research and scientific papers
Charge migration in dicationic electrophiles and its application to the synthesis of aza-polycyclic aromatic compounds
Li, Ang,Kindelin, Patrick J.,Klumpp, Douglas A.
, p. 1233 - 1236 (2006)
Superacid-promoted reactions of dicationic electrophiles have been studied, and the positive charge centers are found to migrate apart in a predictable manner. Using isotopic labeling the charge migration is found in one system to occur through successive deprotonation-reprotonation steps. The charge migration chemistry is the basis for new general synthetic route to aza-polycyclic aromatic compounds.
