942608-40-4

Upstream product

• 862205-27-4 η5-pentamethylcyclopentadienyl(η5-2-(2'-methoxynaphth-1'-yl)-3,4-dimethyl-5-phenylphospholyl)ruthenium(II) 
• 7732-18-5 water 

Downstream Products

• 942608-41-5 2-(2'-trifluoromethanesulfonyloxynaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II) 

Relevant academic research and scientific papers

Planar-to-axial chirality relay in phospharuthenocenes. A rotationally hindered 2-(2′-diphenylphosphinonaphth-1′-yl)phospharuthenocene

Competing steric pressures within the coordination sphere of 2-(2′-X-naphth-1′-yl)-3,4-dimethyl-5-phenyl-η5- phospholyl(pentamethylcyclopentadienyl)ruthenium(II) complexes (X = OMe (1), OH (3), OTf (4), PPh2(O) (5), PPh2 (6)) give rise to a well-defined and predictable axial chirality about the phospharuthenocene- naphthyl bond. Crystal structure analysis of the platinum complex cis-[Pt(6)Cl2] (7) shows a very different geometry from that found in cis-[Pt(1)(PEt3)Cl2] (2) because of the leverage exerted on the Pt coordination sphere by the (2′-PPh2-naphth-1′- yl) functionality.