94294-76-5

Upstream product

• 94347-07-6 (1R*,3R*,4R*,6R*)-6-acetoxy-4-chloro-1,3-dimethyl-3-(4-methyl-3-pentene)-2-oxabicyclo<2.2.2>octane 
• 104643-44-9 (1S,3R,4S,6R)-6-Acetoxy-3-(3,4-dibromo-4-methyl-pentyl)-1,3-dimethyl-2-oxa-bicyclo[2.2.2]octane-4-carboxylic acid 
• 104643-30-3 (1S,3R,4S,6R)-6-Acetoxy-1,3-dimethyl-3-(4-methyl-pent-3-enyl)-2-oxa-bicyclo[2.2.2]octane-4-carboxylic acid 
• 94294-70-9 (1S*,3S*,1R*,1R*)-3,4-epoxy-1-(1,5-dimethyl-1-hydroxy-4-hexene)-4-methyl-3-cyclohexenecarboxylic acid 
• 94294-69-6 (1S,4S,5S)-1-((R)-1-Hydroxy-1,5-dimethyl-hex-4-enyl)-4-iodo-4-methyl-6-oxa-bicyclo[3.2.1]octan-7-one 
• 94294-71-0 (1S,3R,4S,6R)-6-Hydroxy-1,3-dimethyl-3-(4-methyl-pent-3-enyl)-2-oxa-bicyclo[2.2.2]octane-4-carboxylic acid 
• 94294-81-2 (1R*,1R*)-1-(1,5-dimethyl-1-hydroxy-4-hexene)-4-methyl-3-cyclohexenecarboxylic acid 
• 94294-73-2 (1S,3R,4S,6R)-4-Chloro-1,3-dimethyl-3-(4-methyl-pent-3-enyl)-2-oxa-bicyclo[2.2.2]octan-6-ol 
• 94294-72-1 (1S,3R,4S,6R)-4-Chloro-3-(3,4-dibromo-4-methyl-pentyl)-1,3-dimethyl-2-oxa-bicyclo[2.2.2]octan-6-ol 
• 94294-74-3 Acetic acid (1S,3R,4S,6R)-4-chloro-1,3-dimethyl-3-(4-methyl-pent-3-enyl)-2-oxa-bicyclo[2.2.2]oct-6-yl ester 
• 100938-99-6 1-(1-Methyl-7-oxabicyclo<4.1.0>hept-3-en-4-yl)ethanon 
• 110315-50-9 1-<(4,5-trans)-4-Methyl-4,5-bis(tetrahydro-2-pyranyloxy)-1-cyclohexen-1-yl>ethanon 
• 110315-45-2 (1,2-trans)-4-(1'-Hydroxy-1',5'-dimethyl-4'-hexen-1'-yl)-1-methyl-2-(tetrahydro-2''-pyranyloxy)-4-cyclohexen-1-ol 
• 110315-51-0 1-<(4,5-trans)-4-Hydroxy-4-methyl-5-(tetrahydro-2-pyranyloxy)-1-cyclohexen-1-yl>ethanon 

Downstream Products

• 104643-37-0 (1R*,2R*)-2-bromo-1-methyl-4-((Z)-1,5-dimethylhex-4-enylidene)cyclohexan1-ol 
• 104643-35-8 Methanesulfonic acid (1S,2S)-5-[1,5-dimethyl-hex-4-en-(Z)-ylidene]-2-hydroxy-2-methyl-cyclohexyl ester 
• 94294-77-6 Toluene-4-sulfonic acid (1S,2S)-5-[1,5-dimethyl-hex-4-en-(E)-ylidene]-2-hydroxy-2-methyl-cyclohexyl ester 

Relevant academic research and scientific papers

Terpenes and Terpene Derivatives, XXI.- Synthesis of rac-4,5-Dihydro-β-curcumene-4,5-diol

Hydrolysis of the β-curcumene monoepoxide 1 afforded the title compound 2. - A second way started from the epoxy ketone 6.Hydrolysis (-->7), formation of the THP ethers (-->8, -->9), and reaction with homoprenyllithium leads to the allylic alcohol 3.After