943341-59-1Relevant academic research and scientific papers
Palladium-Catalyzed One-Pot Reaction of Hydrazones, Dihaloarenes, and Organoboron Reagents: Synthesis and Cytotoxic Activity of 1,1-Diarylethylene Derivatives
Roche, Maxime,Salim, Salim Mmadi.,Bignon, Jér?me,Levaique, Hélène,Brion, Jean-Daniel,Alami, Mouad,Hamze, Abdallah
, p. 6715 - 6727 (2015/10/06)
A new three-component assembly reaction between N-tosylhydrazones, dihalogenated arenes, and boronic acids or boronate esters was developed, producing highly substituted 1,1-diarylethylenes in good yields. The two C-C bonds formed through this coupling ha
SYSTEM FOR CONTROLLING THE REACTIVITY OF BORONIC ACIDS
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Page/Page column 15, (2009/02/11)
A protected organoboronic acid includes a boron having an sp3 hybridization, a conformationally rigid protecting group bonded to the boron, and an organic group bonded to the boron through a boron-carbon bond. A method of performing a chemical reaction includes contacting a protected organoboronic acid with a reagent, the protected organoboronic acid including a boron having an sp3 hybridization, a conformationally rigid protecting group bonded to the boron, and an organic group bonded to the boron through a boron-carbon bond. The organic group is chemically transformed, and the boron is not chemically transformed.
A simple and modular strategy for small molecule synthesis: Iterative Suzuki-Miyaura coupling of B-protected haloboronic acid building blocks
Gillis, Eric P.,Burke, Martin D.
, p. 6716 - 6717 (2008/02/05)
We herein describe a simple and highly modular strategy for small molecule synthesis involving the iterative cross-coupling of B-protected bifunctional haloboronic acids. Enabling this approach, we have newly discovered that the pyramidalization of boroni
