943435-65-2Relevant academic research and scientific papers
Asymmetric synthesis of γ-hydroxy-α,β-acetylenic esters catalyzed by oxazolidine-titanium complex
Mao, Jincheng,Guo, Jun
, p. 2295 - 2300 (2009)
An efficient catalytic system has been developed for the enantioselective reaction of alkynoates with aromatic aldehydes for the synthesis of optically active γ-hydroxy-α,β-acetylenic esters (with up to 81% isolated yield and up to 84% enantioselectivity)
Highly enantioselective catalytic methyl propiolate addition to both aromatic and aliphatic aldehydes
Huang, Jian,Wei, Siping,Wang, Li,Zhang, Chun,Li, Shuangxun,Liu, Pingxian,Du, Xi,Wang, Qin
, p. 428 - 435 (2016/05/19)
The excellent catalytic effect on methyl propiolate addition to a wide range of aromatic and aliphatic aldehydes promoted by inexpensive and commercially available BINOL-based ligand is reported. The catalyst systems showed high yields and excellent enantioselectivities for aromatic aldehydes, and excellent yields and high enantioselectivities for aliphatic aldehydes.
