943528-40-3Relevant academic research and scientific papers
LIGHT-EMITTING COMPOUNDS FOR LIGHT-EMITTING DEVICES
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Paragraph 0137, (2016/10/31)
Compounds represented by Formula (1) are disclosed herein. Organic light-emitting elements and an organic light-emitting diode devices comprising these compounds are also disclosed.
A simple base-mediated halogenation of acidic sp2 C-H bonds under noncryogenic conditions
Do, Hien-Quang,Daugulis, Olafs
supporting information; experimental part, p. 421 - 423 (2009/07/04)
(Chemical Equation Presented) A new method has been developed for in situ halogenation of acidic sp2 carbon-hydrogen bonds in heterocycles and electron-deficient arenes. Either selective monohalogenation or one-step exhaustive polyhalogenation is possible for substrates possessing several C-H bonds that are flanked by electron-withdrawing groups. For the most acidic arenes, such as pentafluorobenzene, K3PO4 base can be employed instead of BuLi for metalation/halogenation sequences.
In situ generation and trapping of aryllithium and arylpotassium species by halogen, sulfur, and carbon electrophiles
Popov, Ilya,Do, Hien-Quang,Daugulis, Olafs
supporting information; experimental part, p. 8309 - 8313 (2010/01/16)
(Chemical Equation Presented) A general method has been developed for in situ trapping of arylmetal intermediates by halogen, sulfur, ketone, and aldehyde electrophiles affording the functionalization of the most acidic position in arene. Pentafluorobenzene, benzothiazole, and benzoxazole can be functionalized by using K3PO4 base. For less acidic arenes, tBuOLi base is required. Arenes with DMSO pKa values of 35 or less are reactive. 2009 American Chemical Society.
