94354-60-6

Basic information

• Product Name: 1-BENZOYLOXYETHYL ACETATE
• Synonyms: 1-BENZOYLOXYETHYL ACETATE
• CAS NO: 94354-60-6
• Molecular Formula: C₁₁H₁₂O₄
• Molecular Weight: 0
• Mol File: 94354-60-6.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 311°C at 760 mmHg
• Flash Point: 153.5°C
• Appearance: /
• Density: 1.152g/cm³
• Vapor Pressure: 0.000579mmHg at 25°C
• Refractive Index: 1.505
• CAS DataBase Reference: 1-BENZOYLOXYETHYL ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-BENZOYLOXYETHYL ACETATE(94354-60-6)
• EPA Substance Registry System: 1-BENZOYLOXYETHYL ACETATE(94354-60-6)

Safety Data

• Hazardous Substances Data: 94354-60-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H12O4/c1-8(12)14-9(2)15-11(13)10-6-4-3-5-7-10/h3-7,9H,1-2H3

Upstream product

• 141-78-6 ethyl acetate 
• 65-85-0 benzoic acid 
• 100-46-9 benzylamine 
• 536-74-3 phenylacetylene 
• 100-42-5 styrene 
• 7127-19-7 2-phenyl-1,3-oxazoline 
• 64-19-7 acetic acid 

Relevant articles and documents

Generation of bis-Acyl ketals from esters and benzyl amines under oxidative conditions

Treatment of benzylamines with esters at an elevated temperature are expected to give amides. However, in the presence of TBAI/TBHP, esters possessing a methylene carbon α-to oxygen with benzylamines provide bis-esters rather than the expected amides. Benzylamines under oxidative conditions generate less nucleophilic carboxylates, which couples at the sp3 C-H bonds of esters and cyclic ethers to give bis-acyl ketals and α-acyloxy ethers, respectively.

The nitrosation of imidazolines and oxazolines

Nitrosation (HOAc / NaNO2) of 1-methyl-2-phenyl-2-imidazoline 8 results in cleavage of only the C-N single bond and production of N- (2-methylnitrosaminoethyl)-N-nitrosobenzamide 10. In contrast, 2- phenyl-2-oxazoline 9 nitrosates very rapidly to give products (13-16) derived from a diazonium ion arising from the exclusive cleavage of the C=N.