943589-86-4

Basic information

• Product Name: 2-bromo-4-(tert-butyldimethylsilyloxy)cyclohexanone
• Synonyms: 2-bromo-4-(tert-butyldimethylsilyloxy)cyclohexanone
• CAS NO: 943589-86-4
• Molecular Weight: 307.303
• Mol File: 943589-86-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-bromo-4-(tert-butyldimethylsilyloxy)cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-4-(tert-butyldimethylsilyloxy)cyclohexanone(943589-86-4)
• EPA Substance Registry System: 2-bromo-4-(tert-butyldimethylsilyloxy)cyclohexanone(943589-86-4)

Safety Data

• Hazardous Substances Data: 943589-86-4(Hazardous Substances Data)

Upstream product

• 150-76-5 4-methoxy-phenol 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 69125-55-9 4-hydroxy-1-methoxy-1-cyclohexene 
• 137718-78-6 tert-butyl-(4-methoxycyclohex-3-enyloxy)dimethylsilane 

Downstream Products

• 943589-61-5 (3-bromo-4-trifluoromethanesulfonyloxycyclohex-3-enyloxy)-tert-butyldimethylsilane 
• 943589-65-9 tert-butyl (E)-(1''S,3a''R,7a''S)-3-[2'-(1''-tert-butoxy-7a''-methyl-2'',3'',3a'',6'',7'',7a''-hexahydro-1''H-inden-5''-yl)-5'-(tert-butyldimethylsilanyloxy)-cyclohex-1'-enyl]acrylate 
• 943589-64-8 (1'S,3a'R,7a'S)-[3-bromo-4-(1'-tert-butoxy-7a'-methyl-2',3',3a',6',7',7a'-hexahydro-1'H-inden-5'-yl)cyclohex-3-enyloxy]-tert-butyldimethylsilane 

Relevant articles and documents

Stille-heck coupling sequences applied in a versatile new access to steroid skeletons

A variety of enantiomerically pure steroidal compounds was synthesized utilizing a sequence of Stille and Heck cross-coupling reactions and subsequent thermal 6π-electrocyclizations. Highly chemoselective Stille couplings on the triflate moiety of several