94369-75-2

Basic information

• Product Name: 1-Cyclohexene-1-carboxaldehyde, 4-(1-methylethyl)-, (R)-
• CAS NO: 94369-75-2
• Molecular Formula: C10H16O
• Molecular Weight: 152.236
• Mol File: 94369-75-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Cyclohexene-1-carboxaldehyde, 4-(1-methylethyl)-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Cyclohexene-1-carboxaldehyde, 4-(1-methylethyl)-, (R)-(94369-75-2)
• EPA Substance Registry System: 1-Cyclohexene-1-carboxaldehyde, 4-(1-methylethyl)-, (R)-(94369-75-2)

Safety Data

• Hazardous Substances Data: 94369-75-2(Hazardous Substances Data)

Upstream product

• 851520-66-6 (3R)-3-isopropyl-6-methyl-7-oxabicyclo[4.1.0]heptane 
• 499-94-5 (S)-carvomenthene 
• 6153-16-8 (+)-β-phellandrene 
• 7732-18-5 water 
• 1195-31-9 (+)-p-menth-1-ene 

Downstream Products

• 929194-89-8 C₂₆H₃₅N₃O 
• 2153-65-3 (R)-p-menth-1-en-7-al-(2,4-dinitro-phenylhydrazone) 
• 91334-45-1 (R)-phellandral semicarbazone 

Relevant articles and documents

Synthesis of the Alleged Natural Monoterpenoid α-Santolinenone

Authentic α-santolinenone ( = (+)-(4R)-1(7)-p-menthen-2-one; (+)-1) is made available for the first time in 30 percent overall yield from (+)-(4R)-p-menthene ((+)-2) via the diastereomeric allylic alcohols (+)-4a/(+)-4b, which are oxidized to (+)-1 with Ag2CO3/Celite.Yields are good, except for the last stage; indeed, only alcohol (+)-4a, with equatorial OH-group, undergoes oxidation, and (+)-1 is partly substracted via a hetero Diels-Alder dimerization giving a mixture of the diastereomeric dihydropyrans (+)-5a/(+)-5b.When Cr(VI) reagents are used, (+)-4a/(+)-4b mainly give phelandral (6) and carvotanacetone (7).MnO2 reacts too sluggishly with (+)-4a/(+)-4b.A camphor pyrolyzate, previously thought to be 1 must be a different compound, probably 7.