943733-47-9Relevant academic research and scientific papers
Photoswitching of the reactivity involving hydrosilylation of a 1,1,3,3-tetrahydrodisiloxane bearing two azo groups
Yamamura, Masaki,Kano, Naokazu,Kawashima, Takayuki
, p. 4033 - 4036 (2008/02/04)
A pentacoordinate (E,E)-1,1,3,3-tetrahydrodisiloxane bearing two azo groups gave hydrazobenzene in the fluoride ion-induced hydrolysis involving hydrosilylation of the azo groups followed by cleavage of the Si-C bonds, while a tetracoordinate (E,E)-forms formed by its photoirradiation gave an octaarylsilsesquioxane without cleavage of the Si-C bonds.
