943750-33-2

Upstream product

• 27895-61-0 N-allyl-4-bromobenzaldimine 
• 1730-25-2 allylmagnesium bromide 
• 1122-91-4 4-bromo-benzaldehyde 

Downstream Products

• 1629796-20-8 tert-butyl 2-(4-bromophenyl)-3,4-dihydropyridine-1(2H)-carboxylate 
• 943750-34-3 tert-butyl allyl[1-(4-bromophenyl)but-3-enyl]carbamate 

Relevant academic research and scientific papers

Imino glycals via ruthenium-catalyzed RCM and isomerization

N-Allyl-N-homoallylamines were converted in one step into cyclic enamides via a ruthenium-catalyzed assisted tandem catalytic ring-closing metathesis-isomerization sequence. The sequence relies on the in situ transformation of a metathesis active Ru-carbene into an isomerization active Ru-hydride by addition of hydroxide as a chemical trigger.