943768-32-9Relevant academic research and scientific papers
Acid catalyzed stereoselective rearrangement and dimerization of flavenes: synthesis of dependensin
Deodhar, Mandar,Black, David StC,Kumar, Naresh
, p. 5227 - 5235 (2008/02/01)
Appropriately substituted flavenes undergo stereoselective rearrangement and dimerization when treated with methanolic hydrochloric acid to give benzopyranobenzopyrans. A rationale for the rearrangement is proposed. This synthetic methodology has been used for a high yield synthesis of the natural product dependensin.
