943784-98-3Relevant articles and documents
Studies toward the total synthesis of grandisine a: Synthesis of 9-epi-grandisine A
Maloney, David J.,Danishefsky, Samuel J.
, p. 167 - 174 (2008/02/13)
A concise synthesis of 9-epi-grandisine A is described, which makes use of a Lewis acid-promoted hetero-Diels-Alder reaction to construct the tricyclic skeleton. Attempts to obtain grandisine A through a late-stage controlled epimerization are also discussed.