94397-57-6Relevant academic research and scientific papers
STEREOSELECTIVE ADDITION OF α-CHLORO ALLYLIC CHROMIUM REAGENTS TO ALDEHYDES
Takai, Kazuhiko,Kataoka, Yasutaka,Utimoto, Kiitiro
, p. 4389 - 4392 (2007/10/02)
Treatment of a solution of 1,1-dichloro-2-butene and benzaldehyde with CrCl2 in THF-DMF at 25 deg C for 1 h gave threo-(Z)-4-chloro-2-methyl-1-phenyl-3-buten-1-ol in 96percent yield under high stereocontrol.
A NOVEL AND CONVENIENT REGIO-CONTROLLED SYNTHESIS OF α-HALOGEN-SUBSTITUTED ALLYLSILANES. STEREOSELECTIVE SYNTHESIS OF Z-ALKENYL HALIDES
Hosomi, Akira,Ando, Masatomo,Sakurai, Hideki
, p. 1385 - 1388 (2007/10/02)
α-Halogen-substituted allylsilanes, prepared conveniently by the in situ reaction of lithiated allyl halides with chlorosilane in a regio-controlled manner, react with various electrophiles to give the corresponding alkenyl halides with high Z preference.
