94397-76-9Relevant academic research and scientific papers
1,4-Dithia-2,6-diaza-3,5-diborinanes: A Novel B-N-S-Ringsystem
Habben, Carl,Meller, Anton
, p. 1022 - 1026 (2007/10/02)
The novel 1,4-dithia-2,6-diaza-3,5-diborinane ring system results from the reaction of 3,5-dialkyl- (or di-sec.amino-) substituted 1,2,4-trithia-3,5-diborolanes with 1,3-disubstituted sulfurdiimides by replacement of the disulfane bridge.Upon treatment with azomethines, 3,5-dibromo-1,2,4-trithia-3,5-diborolane gives 3,5-dibromo-1,2-dithia-4-aza-5-diborolidines by substitution of the sulfur atom in position 4. 1H, 11B, 13C, 29Si NMR and mass spectra are reported and discussed. - Keywords: 1,4-Dithia-2,6-diaza-3,5-diborinanes, 1,2-Dithia-4-aza-3,5-diborolidines, 1,2,4-Trithia-3,5-diborolanes, Sulfurdiimides, Azomethines
