944069-58-3Relevant academic research and scientific papers
Thermal Dehydrogenation of Base-Stabilized B2H5+ Complexes and Its Role in C-H Borylation
Prokofjevs, Aleksandrs
, p. 13401 - 13405 (2015)
Thermally induced dehydrogenation of the H-bridged cation L2B2H5+ (L=Lewis base) is proposed to be the key step in the intramolecular C-H borylation of tertiary amine boranes activated with catalytic amounts of
N-directed aliphatic C-H borylation using borenium cation equivalents
Prokofjevs, Aleksandrs,Vedejs, Edwin
, p. 20056 - 20059 (2012/02/05)
Highly electrophilic boron cations derived from hindered amine borane complexes have been shown to undergo intramolecular aliphatic C-H borylation.
Electrophilic activation of Lewis base complexes of borane with trityl tetrakis(pentafluorophenyl)borate
De Vries, Timothy S.,Vedejs, Edwin
, p. 3079 - 3081 (2008/10/09)
Borenium ions do not accumulate under the conditions of hydride abstraction from Lewis base borane complexes (L·BH3) using trityl cation because subsequent rapid reaction with L·BH3 occurs to form B - H - B bonds. The hydride-bridged
