944131-47-9Relevant academic research and scientific papers
Enantioselective reductive coupling of acetylene to N-arylsulfonyl imines via rhodium catalyzed C-C bond-forming hydrogenation: (Z)-dienyl allylic amines
Skucas, Eduardas,Kong, Jong Rock,Krische, Michael J.
, p. 7242 - 7243 (2008/02/08)
The first highly enantioselective catalytic vinylation of aldimines to furnish allylic amines is reported. Exposure of aromatic and aliphatic N-arylsulfonyl aldimines 1a-12a to equal volumes of acetylene and hydrogen gas at 45 °C and ambient pressure in t
